Structural and fluorescent characterizations of one- and two-dimensional Cd(II) metal-organic frameworks

被引：19
|
作者：
Yao, Ya-li [1 ]
Che, Yun-Xia [1 ]
Zheng, Ji-Min [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 08期
基金：
中国国家自然科学基金;
关键词：
cadmium(II); crystal structure; metal-organic frameworks; luminescent property;
D O I：
10.1016/j.inoche.2008.04.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Benzimidazole-5-carboxylate (HL1) and 5-methylbenzimidazole-6-carboxylic acid (HL2) have been employed to assemble with Cd(II) ions under hydrothermal conditions, leading to the generation of 1D (1) and 2D (2) metal-organic frameworks. The two coordinated water molecules of cadmium in 1 restrain the carboxylic moiety from adopting a bidentate chelating coordination mode, which seems to be an important factor in the dramatic structural change from 1D to 2D. Both complexes display blue emission in the solid state and the luminescent properties relate to their structures. (c) 2008 Published by Elsevier B.V.
引用
收藏
页码：883 / 885
页数：3
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