NMR studies on the diffusion of hydrocarbons on the metal-organic framework material MOF-5

被引：194
|
作者：
Stallmach, F
Gröger, S
Künzel, V
Kärger, J
Yaghi, OM
Hesse, M
Müller, U
机构：
[1] Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany
[2] BASF AG, D-67056 Ludwigshafen, Germany
[3] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期
关键词：
alkanes; benzene; diffusion; microporous materials; NMR spectroscopy;
D O I：
10.1002/anie.200502553
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the move: High intracrystalline mobilities and fast exchange between the crystal and the surrounding gas phase were found in NMR studies on the diffusion of methane, ethane, n-hexane, and benzene in large crystals of the metal-organic framework MOF-5 (see SEM image). The results support future use of metal-organic framework materials as tailorable sorbents for fast gas processing and gas-storage materials in industry. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2123 / 2126
页数：4
相关论文
共 50 条
  • [31] Antibacterial Films of Composite Materials Based on the Biocompatible Metal-Organic Framework MOF-5 and Hydrocolloids
    Pak, A. M.
    Zakharchenko, E. N.
    Korlyukov, A. A.
    Novikov, V. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2022, 48 (04) : 195 - 200
  • [32] Metal-Organic Framework (MOF)-A Universal Material for Biomedicine
    Vodyashkin, Andrey A.
    Sergorodceva, Antonina V.
    Kezimana, Parfait
    Stanishevskiy, Yaroslav M.
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2023, 24 (09)
  • [33] Application of Taguchi orthogonal array in optimization of the synthesis and crystallinity of metal-organic framework-5 (MOF-5)
    Al-Jarsha, Hayder Yahya Mansoor
    Ghareeb, Mowafaq M.
    TROPICAL JOURNAL OF PHARMACEUTICAL RESEARCH, 2023, 22 (12) : 2473 - 2482
  • [34] Gas Separation Properties of Metal Organic Framework (MOF-5) Membranes
    Zhao, Zhenxia
    Ma, Xiaoli
    Kasik, Alexandra
    Li, Zhong
    Lin, Y. S.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (03) : 1102 - 1108
  • [35] Investigation of Metal-Organic Framework-5 (MOF-5) as an Antitumor Drug Oridonin Sustained Release Carrier
    Chen, Gongsen
    Luo, Juyuan
    Cai, Mengru
    Qin, Liuying
    Wang, Yibo
    Gao, Lili
    Huang, Pingqing
    Yu, Yingchao
    Ding, Yangming
    Dong, Xiaoxv
    Yin, Xingbin
    Ni, Jian
    MOLECULES, 2019, 24 (18):
  • [36] Thermal conductivity of metal-organic framework 5 (MOF-5): Part I. Molecular dynamics simulations
    Huang, B. L.
    McGaughey, A. J. H.
    Kaviany, M.
    INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2007, 50 (3-4) : 393 - 404
  • [37] New method for catalyst preparation based on metal-organic framework MOF-5 for the partial hydrogenation of phenylacetylene
    Belyaeva, E. V.
    Isaeva, V. I.
    Said-Galiev, E. E.
    Tkachenko, O. P.
    Savilov, S. V.
    Egorov, A. V.
    Kozlova, L. M.
    Sharf, V. Z.
    Kustov, L. M.
    RUSSIAN CHEMICAL BULLETIN, 2014, 63 (02) : 396 - 403
  • [38] Ab initio parametrized MM3 force field for the metal-organic framework MOF-5
    Tafipolsky, Maxim
    Amirjalayer, Saeed
    Schmid, Rochus
    JOURNAL OF COMPUTATIONAL CHEMISTRY, 2007, 28 (07) : 1169 - 1176
  • [39] Solvothermal Synthesis of the Metal-Organic Framework MOF-5 in Autoclaves Prepared by 3D Printing
    Denisov, G. L.
    Primakov, P. V.
    Korlyukov, A. A.
    Novikov, V. V.
    Nelyubina, Yu. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (12) : 836 - 842
  • [40] Theoretical Investigations on the Chemical Bonding, Electronic Structure, And Optical Properties of the Metal-Organic Framework MOF-5
    Yang, Li-Ming
    Vajeeston, Ponniah
    Ravindran, Ponniah
    Fjellvag, Helmer
    Tilset, Mats
    INORGANIC CHEMISTRY, 2010, 49 (22) : 10283 - 10290
12345