NMR studies on the diffusion of hydrocarbons on the metal-organic framework material MOF-5

被引：194
|
作者：
Stallmach, F
Gröger, S
Künzel, V
Kärger, J
Yaghi, OM
Hesse, M
Müller, U
机构：
[1] Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany
[2] BASF AG, D-67056 Ludwigshafen, Germany
[3] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期
关键词：
alkanes; benzene; diffusion; microporous materials; NMR spectroscopy;
D O I：
10.1002/anie.200502553
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the move: High intracrystalline mobilities and fast exchange between the crystal and the surrounding gas phase were found in NMR studies on the diffusion of methane, ethane, n-hexane, and benzene in large crystals of the metal-organic framework MOF-5 (see SEM image). The results support future use of metal-organic framework materials as tailorable sorbents for fast gas processing and gas-storage materials in industry. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2123 / 2126
页数：4
相关论文
共 50 条
  • [21] Ferrocene in the metal-organic framework MOF-5 studied by homo- and heteronuclear correlation NMR and MD simulation
    Wehring, M.
    Magusin, P. C. M. M.
    Amirjalayer, S.
    Schmid, R.
    Stallmach, F.
    MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 186 : 130 - 136
  • [22] Metal Substitutions in the MOF-5 Metal-Organic Framework: A Hybrid Density Functional Theory Study
    Orellana, Walter
    JOURNAL OF PHYSICAL CHEMISTRY C, 2024, 128 (15): : 6471 - 6477
  • [23] Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
    Huang, B. L.
    Ni, Z.
    Millward, A.
    McGaughey, A. J. H.
    Uher, C.
    Kaviany, M.
    Yaghi, O.
    INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2007, 50 (3-4) : 405 - 411
  • [24] Metal-organic framework (MOF-5) incorporated on NiCo2O4 as electrode material for supercapacitor application
    Kishore babu, S.
    Jayachandran, M.
    Maiyalagan, T.
    Vijayakumar, T.
    Gunasekaran, B.
    Materials Letters, 2021, 302
  • [25] Metal-organic framework (MOF-5) incorporated on NiCo2O4 as electrode material for supercapacitor application
    Babu, S. Kishore
    Jayachandran, M.
    Maiyalagan, T.
    Vijayakumar, T.
    Gunasekaran, B.
    MATERIALS LETTERS, 2021, 302
  • [26] Amorphization of Metal–Organic Framework MOF-5 by Electrical Discharge
    You Zhou
    Chang-jun Liu
    Plasma Chemistry and Plasma Processing, 2011, 31 : 499 - 506
  • [27] Nonsurfactant Synthesis and Characterizations of Metal-Organic Framework MOF-5 Materials Using Fatty Alcohols
    Misran, H.
    Othman, S. Z.
    Manap, A.
    Pauzi, N. I. M.
    Ramesh, S.
    SCIENCE OF ADVANCED MATERIALS, 2014, 6 (07) : 1638 - 1644
  • [28] Hydrogen adsorption equilibrium and kinetics in metal-organic framework (MOF-5) synthesized with DEF approach
    Saha, Dipendu
    Wei, Zuojun
    Deng, Shuguang
    SEPARATION AND PURIFICATION TECHNOLOGY, 2009, 64 (03) : 280 - 287
  • [29] Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour
    Bordiga, S
    Lamberti, C
    Ricchiardi, G
    Regli, L
    Bonino, F
    Damin, A
    Lillerud, KP
    Bjorgen, M
    Zecchina, A
    CHEMICAL COMMUNICATIONS, 2004, (20) : 2300 - 2301
  • [30] Intercalation of Coordinatively Unsaturated FeIII Ion within Interpenetrated Metal-Organic Framework MOF-5
    Holmberg, Rebecca J.
    Burns, Thomas
    Greer, Samuel M.
    Kobera, Libor
    Stoian, Sebastian A.
    Korobkov, Ilia
    Hill, Stephen
    Bryce, David L.
    Woo, Tom K.
    Murugesu, Muralee
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (23) : 7711 - 7715
12345