NMR studies on the diffusion of hydrocarbons on the metal-organic framework material MOF-5

被引：194
|
作者：
Stallmach, F
Gröger, S
Künzel, V
Kärger, J
Yaghi, OM
Hesse, M
Müller, U
机构：
[1] Univ Leipzig, Fak Phys & Geowissensch, D-04103 Leipzig, Germany
[2] BASF AG, D-67056 Ludwigshafen, Germany
[3] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期
关键词：
alkanes; benzene; diffusion; microporous materials; NMR spectroscopy;
D O I：
10.1002/anie.200502553
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the move: High intracrystalline mobilities and fast exchange between the crystal and the surrounding gas phase were found in NMR studies on the diffusion of methane, ethane, n-hexane, and benzene in large crystals of the metal-organic framework MOF-5 (see SEM image). The results support future use of metal-organic framework materials as tailorable sorbents for fast gas processing and gas-storage materials in industry. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2123 / 2126
页数：4
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