Radical copolymerization of 1,5,9-cyclododecatriene with maleic anhydride

被引：0

作者：

Medyakova, LV ^{[1
]}

Mamedov, AS ^{[1
]}

Rzaeva, SA ^{[1
]}

Babaev, SB ^{[1
]}

Dunyamaliev, AD ^{[1
]}

Lezgiev, NY ^{[1
]}

机构：

[1] Azerbaijan Acad Sci, Inst Polymer Mat, Sumgait 373204, Azerbaijan

来源：

VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1999年 / 41卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymerizatian of 1,5,9-cyclododecatriene (a mixture of trans-trans-trans and cis-trans-trans isomers) with maleic anhydride was studied in dioxane in the presence of benzoyl peroxide. As shown with IR spectroscopy, the copolymerization process is preceded by a partial spatial cis-rr uns isomerization of cyclododecatriene. It is suggested that the formation of an unsaturated alternating copolymer with an composition close to 1 : 2 proceeds by the mechanism of cyclocopolymerization involving an intermolecular complex formed between cyclododecatriene and maleic anhydride in the elementary events of chain propagation.

引用

页码：877 / 880

页数：4

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