[(C4H12N)2][Zn3(HPO3)4]:: An open-framework zinc phosphite containing extra-large 24-ring channels

被引：158

作者：

Liang, J ^{[1
]}

Li, JY ^{[1
]}

Yu, JH ^{[1
]}

Chen, P ^{[1
]}

Fang, QR ^{[1
]}

Sun, FX ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130012, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 16期

关键词：

hydrothermal synthesis; materials science; phosphites; template synthesis; zinc;

D O I：

10.1002/anie.200504134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Hydrothermal reaction of Zn(OAc)2·2 H2O and H3PO3 in the presence of n-butyl-amine gives the title compound, which contains extra-large 24-ring channels (see framework representation). Each channel is enclosed by a tetragonal array of four 8-ring channels interconnected by corner-sharing 4-ring chains through Zn-O-P linkages. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2546 / 2548

页数：3

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