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[(C4H12N)2][Zn3(HPO3)4]:: An open-framework zinc phosphite containing extra-large 24-ring channels
被引:158
|作者:
Liang, J
[1
]
Li, JY
[1
]
Yu, JH
[1
]
Chen, P
[1
]
Fang, QR
[1
]
Sun, FX
[1
]
Xu, RR
[1
]
机构:
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130012, Peoples R China
关键词:
hydrothermal synthesis;
materials science;
phosphites;
template synthesis;
zinc;
D O I:
10.1002/anie.200504134
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
(Figure Presented) Hydrothermal reaction of Zn(OAc)2·2 H2O and H3PO3 in the presence of n-butyl-amine gives the title compound, which contains extra-large 24-ring channels (see framework representation). Each channel is enclosed by a tetragonal array of four 8-ring channels interconnected by corner-sharing 4-ring chains through Zn-O-P linkages. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:2546 / 2548
页数:3
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