[(C4H12N)2][Zn3(HPO3)4]:: An open-framework zinc phosphite containing extra-large 24-ring channels

被引:158
|
作者
Liang, J [1 ]
Li, JY [1 ]
Yu, JH [1 ]
Chen, P [1 ]
Fang, QR [1 ]
Sun, FX [1 ]
Xu, RR [1 ]
机构
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130012, Peoples R China
关键词
hydrothermal synthesis; materials science; phosphites; template synthesis; zinc;
D O I
10.1002/anie.200504134
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Hydrothermal reaction of Zn(OAc)2·2 H2O and H3PO3 in the presence of n-butyl-amine gives the title compound, which contains extra-large 24-ring channels (see framework representation). Each channel is enclosed by a tetragonal array of four 8-ring channels interconnected by corner-sharing 4-ring chains through Zn-O-P linkages. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2546 / 2548
页数:3
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