Structural studies of thermal- and light-induced transitions in iron(II) spin-crossover complexes

被引：16
|
作者：
Thompson, AL [1 ]
Money, VA [1 ]
Goeta, AE [1 ]
Howard, JAK [1 ]
机构：
[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England
来源：
COMPTES RENDUS CHIMIE | 2005年 / 8卷 / 9-10期
关键词：
spin-crossover; spin transition; molecular magnetism; crystal structure; LIESST; variable temperature diffraction studies; iron(II) complexes; coordination polymers; polymorphism; allosterism;
D O I：
10.1016/j.crci.2004.09.020
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Since the spin-crossover (SCO) effect was first discovered, considerable efforts have been made to study compounds that exhibit this phenomenon. Herein we present a selection of our most exciting results from structural studies carried out on some of the fascinating iron(II) SCO compounds we have investigated over the past few years. We discuss a range of compounds from mononuclear to bimetallic polymeric complexes.
引用
收藏
页码：1365 / 1373
页数：9
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