Thermal and light induced spin crossover in a mononuclear iron(II) complex

被引：21

作者：

Wang, Jun-Li ^{[1
]}

Liu, Qiang ^{[1
]}

Lv, Xiao-Jin ^{[1
]}

Duan, Chun-Ying ^{[1
]}

Liu, Tao ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 85卷

关键词：

Spin crossover; Photomagnetism; Iron; Magnetic properties; TRANSITION; STATE; POLYMORPHISM; BISTABILITY; PRESSURE; SYSTEM;

D O I：

10.1016/j.inoche.2017.05.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A mononuclear complex {Fe(L)(2)[N(CN)(2)](2)} (1) has been synthesized through the reaction of (naphth-1-yl)-N-(3,5-di(pyridin-2-yl)-4H-1,2,4-triazol-4-yl)methanimine (L) with Fe[N(CN)(2)](2). Magnetic measurement reveals that 1 exhibits a thermal induced one-step spin crossover behavior with transition temperature T-1/2 of 75 K. Furthermore, the light induced excited spin state trapping effect is observed on 1. (C) 2017 Published by Elsevier B.V.

引用

页码：37 / 40

页数：4

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