Thermal and light induced spin crossover in a mononuclear iron(II) complex

被引：21
|
作者：
Wang, Jun-Li [1 ]
Liu, Qiang [1 ]
Lv, Xiao-Jin [1 ]
Duan, Chun-Ying [1 ]
Liu, Tao [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 85卷
关键词：
Spin crossover; Photomagnetism; Iron; Magnetic properties; TRANSITION; STATE; POLYMORPHISM; BISTABILITY; PRESSURE; SYSTEM;
D O I：
10.1016/j.inoche.2017.05.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A mononuclear complex {Fe(L)(2)[N(CN)(2)](2)} (1) has been synthesized through the reaction of (naphth-1-yl)-N-(3,5-di(pyridin-2-yl)-4H-1,2,4-triazol-4-yl)methanimine (L) with Fe[N(CN)(2)](2). Magnetic measurement reveals that 1 exhibits a thermal induced one-step spin crossover behavior with transition temperature T-1/2 of 75 K. Furthermore, the light induced excited spin state trapping effect is observed on 1. (C) 2017 Published by Elsevier B.V.
引用
收藏
页码：37 / 40
页数：4
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