Oxidation of organic substrates using two triethylammonium halochromates(VI), (C2H5)3NH[CrO3X], (X=F, Cl) supported on silica gel

被引:4
|
作者
Ghammamy, Shahriare [1 ]
Dastpeyman, Samaneh [1 ]
机构
[1] Imani Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin, Iran
关键词
triethylammonium fluorochromate(VI); triethylammonium chlorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols;
D O I
10.1002/jccs.200800034
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Triethylammonium fluorochromate(VI), (C2H5)(3)NHCrO3F, TriEAFC and triethylammonium chlorochromate(VI), (C2H5)(3)NHCrO3Cl, TriEACC were prepared, supported on silica gel and used to quantitatively oxidize a number of organic substrates. These supported triethylammonium halochromates are versatile reagents ensuring effective oxidation of organic compounds, in particular of alcohols, under mild conditions. The durability, ease of work up and efficiency of TriEAFC and TriEACC are considerably increased upon their absorption on silica gel.
引用
收藏
页码:229 / 232
页数:4
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