Oxidation of organic substrates using two triethylammonium halochromates(VI), (C2H5)3NH[CrO3X], (X=F, Cl) supported on silica gel

被引：4

作者：

Ghammamy, Shahriare ^{[1
]}

Dastpeyman, Samaneh ^{[1
]}

机构：

[1] Imani Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin, Iran

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2008年 / 55卷 / 01期

关键词：

triethylammonium fluorochromate(VI); triethylammonium chlorochromate(VI); heterogeneous oxidants; silica gel; oxidation; alcohols;

D O I：

10.1002/jccs.200800034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triethylammonium fluorochromate(VI), (C2H5)(3)NHCrO3F, TriEAFC and triethylammonium chlorochromate(VI), (C2H5)(3)NHCrO3Cl, TriEACC were prepared, supported on silica gel and used to quantitatively oxidize a number of organic substrates. These supported triethylammonium halochromates are versatile reagents ensuring effective oxidation of organic compounds, in particular of alcohols, under mild conditions. The durability, ease of work up and efficiency of TriEAFC and TriEACC are considerably increased upon their absorption on silica gel.

引用

页码：229 / 232

页数：4

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