The transition products in substitutional photochemistry of [Mo(CN)8]4- -: theoretical approach.: X-ray crystal structure of (AsPh4)[W(bpy)(CN)6]

被引：8
|
作者：
Stawski, T [1 ]
Szklarzewicz, J [1 ]
Lewinski, K [1 ]
机构：
[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
来源：
TRANSITION METAL CHEMISTRY | 2006年 / 31卷 / 03期
关键词：
D O I：
10.1007/s11243-005-6416-x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The single crystal X-ray structure of (AsPh4)[W(bpy)(CN)(6)] is described. The structure of octa- and hepta-coordinated intermediates of substitutional photolysis of [Mo(CN)(8)](4-) ion in aqueous media were determined by performing semi-empirical calculations. On the basis of obtained results as well as on empirical data the photolysis scheme has been postulated.
引用
收藏
页码：353 / 361
页数：9
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