The transition products in substitutional photochemistry of [Mo(CN)8]4- -: theoretical approach.: X-ray crystal structure of (AsPh4)[W(bpy)(CN)6]

被引：8

作者：

Stawski, T ^{[1
]}

Szklarzewicz, J ^{[1
]}

Lewinski, K ^{[1
]}

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

来源：

TRANSITION METAL CHEMISTRY | 2006年 / 31卷 / 03期

关键词：

D O I：

10.1007/s11243-005-6416-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The single crystal X-ray structure of (AsPh4)[W(bpy)(CN)(6)] is described. The structure of octa- and hepta-coordinated intermediates of substitutional photolysis of [Mo(CN)(8)](4-) ion in aqueous media were determined by performing semi-empirical calculations. On the basis of obtained results as well as on empirical data the photolysis scheme has been postulated.

引用

页码：353 / 361

页数：9

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