The mixed-valence coordination polymer [Cu(S2CNPr2)2]2[ClO4] containing alternating square-planar Cu(II) and Cu(III) centres

被引：6
|
作者：
Hogarth, Graeme [1 ]
Faulkner, Simon [1 ]
机构：
[1] UCL, Dept Chem, London WC1H 0AJ, England
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 35卷
关键词：
Mixed-valence; Coordination polymer; Dithiocarbamate; Copper(III); Copper(II); CRYSTAL-STRUCTURES; DITHIOCARBAMATE COMPLEXES; MOLECULAR-STRUCTURE; COPPER; LIGAND; CU; DISPROPORTIONATION; SCIENCE; UNITS; ION;
D O I：
10.1016/j.inoche.2013.05.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The mixed-valence coordination polymer, [Cu(S2CNPr2)(2)](2)[ClO4], containing both square-planar Cu(II) and Cu(III) centres, has been prepared and crystallographically characterised. In the solid-state it consists of a chain of alternating Cu(II) and Cu(III) centres held together by intermolecular Cu-S interactions, while the perchlorate anions are not metal coordinated. For comparison the crystal structure of [Cu(S2CNPr2)(2)](2) has been re-determined at 150 K. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：65 / 68
页数：4
相关论文
共 50 条
  • [31] Crystal structures of copper(III) dithiocarbamate complexes [Cu(η2-S2CNMe2)2][ClO4] and [Cu(η2-S2CNEt2)2][FeCl4] with and without anion-cation interactions
    Hogarth, G
    Pateman, A
    Redmond, SP
    INORGANICA CHIMICA ACTA, 2000, 306 (02) : 232 - 236
  • [32] Anomalous Spin-Flop in Antiferromagnetic Cu(pz)2(ClO4)2
    Marchenko, V. I.
    JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS, 2021, 132 (04) : 586 - 587
  • [33] Anomalous Spin-Flop in Antiferromagnetic Cu(pz)2(ClO4)2
    V. I. Marchenko
    Journal of Experimental and Theoretical Physics, 2021, 132 : 586 - 587
  • [34] Synthesis and Crystal Structure of 2D Coordination Polymer {[Cu(dps)2(DMSO)2](ClO4)2}n Based on 4,4′-Dipyridyl Sulfide
    A. N. Morozov
    L. D. Popov
    V. V. Tkachev
    E. A. Raspopova
    V. A. Chetverikova
    S. N. Lyubchenko
    G. V. Shilov
    Russian Journal of General Chemistry, 2019, 89 : 82 - 86
  • [35] A2Cu2CoO2S2 (A = Sr, Ba), a novel example of a square-planar CoO2 layer
    Zhu, WJ
    Hor, PH
    Jacobson, AJ
    Crisci, G
    Albright, TA
    Wang, SH
    Vogt, T
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (50) : 12398 - 12399
  • [36] First dicopper(II) complex to contain bridging macrocyclic pyridazine units: Structure, electrochemistry and magnetochemistry of [Cu(2)L(MeCN)(2)(ClO4)(2)][ClO4](2)
    Brooker, S
    Kelly, RK
    Moubaraki, B
    Murray, KS
    CHEMICAL COMMUNICATIONS, 1996, (22) : 2579 - 2580
  • [37] Noncentrosymmetric Mixed-Valence Copper(I, II) Chloride Framework: β-[Cu(II)(en)2]2Cu(I)7Cl11
    Kang, Jaeun
    Lee, Yumi
    Kim, Seung-Joo
    Yun, Hoseop
    Do, Junghwan
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2015, 36 (12): : 2948 - 2951
  • [38] Rational design of homo and hetero hexanuclear coordination compounds:: Syntheses and magnetic properties of [Cu2IIM4II] (M = Cu, Ni) species and the crystal structure of {[Cu(tmen)(H2O)]2[Cu(tmen)]2[Cu2L] (H2O)}(ClO4)4•2 H2O
    Aukauloo, A
    Ottenwaelder, X
    Ruiz, R
    Journaux, Y
    Pei, Y
    Rivière, E
    Muñoz, MC
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (05) : 951 - 957
  • [39] Synthesis and crystal structures of one-dimensional ClO4- bridged coordination polymers:: {[Cu(Bpy)2(μ2-ClO4)]•ClO4}n and {[Cu2(L-arg)2(Bpy)2(μ2-ClO4)2]•2ClO4-4H2O}n
    Zhou, XH
    Yang, C
    Le, XY
    Chen, S
    Liu, JZ
    Huang, ZJ
    JOURNAL OF COORDINATION CHEMISTRY, 2004, 57 (05) : 401 - 409
  • [40] PREPARATION AND PROPERTIES OF THE TRIPLY BRIDGED, FERROMAGNETICALLY COUPLED DINUCLEAR COPPER(II) COMPLEXES [CU2(OAC)3(BPY)2](CLO4) AND [CU2(OH)(H2O)(OAC)(BPY)2](CLO4)2
    CHRISTOU, G
    PERLEPES, SP
    LIBBY, E
    FOLTING, K
    HUFFMAN, JC
    WEBB, RJ
    HENDRICKSON, DN
    INORGANIC CHEMISTRY, 1990, 29 (19) : 3657 - 3666
12345