The mixed-valence coordination polymer [Cu(S2CNPr2)2]2[ClO4] containing alternating square-planar Cu(II) and Cu(III) centres

被引：6
|
作者：
Hogarth, Graeme [1 ]
Faulkner, Simon [1 ]
机构：
[1] UCL, Dept Chem, London WC1H 0AJ, England
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 35卷
关键词：
Mixed-valence; Coordination polymer; Dithiocarbamate; Copper(III); Copper(II); CRYSTAL-STRUCTURES; DITHIOCARBAMATE COMPLEXES; MOLECULAR-STRUCTURE; COPPER; LIGAND; CU; DISPROPORTIONATION; SCIENCE; UNITS; ION;
D O I：
10.1016/j.inoche.2013.05.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The mixed-valence coordination polymer, [Cu(S2CNPr2)(2)](2)[ClO4], containing both square-planar Cu(II) and Cu(III) centres, has been prepared and crystallographically characterised. In the solid-state it consists of a chain of alternating Cu(II) and Cu(III) centres held together by intermolecular Cu-S interactions, while the perchlorate anions are not metal coordinated. For comparison the crystal structure of [Cu(S2CNPr2)(2)](2) has been re-determined at 150 K. (C) 2013 Elsevier B.V. All rights reserved.
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页码：65 / 68
页数：4
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