1,2,4,5-Tetrakis(phenylsulfonyl)benzene: a novel quadruped host with D2 symmetry having ordered sulfolane and cycloheptanone guests

被引：1

作者：

Farrugia, Louis J. ^{[1
]}

Gall, James H. ^{[1
]}

MacNicol, David D. ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 86期

关键词：

CONFORMATIONS;

D O I：

10.1039/c2cc35647c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title tetrasulfone 1, in common with higher members of the multi-armed aromatic hosts, forms host-guest complexes with polar guest molecules. In the sulfolane and cycloheptanone complexes the host molecule possesses an abab conformation with exact C-2, and approximate D-2 symmetry with deviations owing to crystal packing forces. The conformation of the well-ordered cycloheptanone molecule, which normally undergoes facile pseudorotation, is unambiguously defined in the voids of the crystalline inclusion compound.

引用

页码：10600 / 10602

页数：3

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