1,2,4,5-Tetrakis(phenylsulfonyl)benzene: a novel quadruped host with D2 symmetry having ordered sulfolane and cycloheptanone guests

被引：1
|
作者：
Farrugia, Louis J. [1 ]
Gall, James H. [1 ]
MacNicol, David D. [1 ]
机构：
[1] Univ Glasgow, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 86期
关键词：
CONFORMATIONS;
D O I：
10.1039/c2cc35647c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title tetrasulfone 1, in common with higher members of the multi-armed aromatic hosts, forms host-guest complexes with polar guest molecules. In the sulfolane and cycloheptanone complexes the host molecule possesses an abab conformation with exact C-2, and approximate D-2 symmetry with deviations owing to crystal packing forces. The conformation of the well-ordered cycloheptanone molecule, which normally undergoes facile pseudorotation, is unambiguously defined in the voids of the crystalline inclusion compound.
引用
收藏
页码：10600 / 10602
页数：3
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