Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins

被引：68

作者：

Guo, Siyu ^{[1
]}

Yang, Peng ^{[1
]}

Zhou, Jianrong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 60期

关键词：

HIGHLY ENANTIOSELECTIVE HYDROGENATION; SUBSTITUTED ACRYLIC-ACIDS; FORMIC-ACID; HOMOGENEOUS HYDROGENATION; LIGANDS; COMPLEXES; ALPHA; REDUCTION; MECHANISM; DEHYDROGENATION;

D O I：

10.1039/c5cc01632k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly sigma-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation of resulting nickel enolates.

引用

页码：12115 / 12117

页数：3

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