Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins

被引：68

作者：

Guo, Siyu ^{[1
]}

Yang, Peng ^{[1
]}

Zhou, Jianrong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 60期

关键词：

HIGHLY ENANTIOSELECTIVE HYDROGENATION; SUBSTITUTED ACRYLIC-ACIDS; FORMIC-ACID; HOMOGENEOUS HYDROGENATION; LIGANDS; COMPLEXES; ALPHA; REDUCTION; MECHANISM; DEHYDROGENATION;

D O I：

10.1039/c5cc01632k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly sigma-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation of resulting nickel enolates.

引用

页码：12115 / 12117

页数：3

共 50 条

[21] STEREOCHEMISTRY OF THE NICKEL-CATALYZED HYDROCYANATION OF OLEFINS
BACKVALL, JE
ANDELL, OS
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (21) : 1098 - 1099
[22] Proton-Promoted Nickel-Catalyzed Asymmetric Hydrogenation of Aliphatic Ketoacids
Deng, Chen-Qiang
Liu, Jiao
Luo, Jia-Hao
Gan, Li-Jin
Deng, Jin
Fu, Yao
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (15)
[23] Nickel-Catalyzed Hydroamination of Olefins with Anthranils
Gao, Yang
Cui, Yushan
Huo, Yanping
Chen, Jinhong
She, Minwei
Li, Xianwei
Chen, Qian
Hu, Xiao-Qiang
JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (17): : 12107 - 12118
[24] Selective nickel-catalyzed fluoroalkylations of olefins
Zhang, Shaoke
Weniger, Florian
Ye, Fei
Rabeah, Jabor
Ellinger, Stefan
Zaragoza, Florencio
Taeschler, Christoph
Neumann, Helfried
Brueckner, Angelika
Beller, Matthias
CHEMICAL COMMUNICATIONS, 2020, 56 (96) : 15157 - 15160
[25] NICKEL-CATALYZED EPOXIDATION OF OLEFINS WITH NAOCL
YAMAZAKI, S
YAMAZAKI, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (10) : 3185 - 3187
[26] NICKEL-CATALYZED HYDROGENATION OF COMMERCIAL ALDOL
HANCOCK, CK
HENSON, DD
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1953, 45 (03): : 629 - 632
[27] STUDIES OF THE NICKEL-CATALYZED HYDROGENATION OF GRAPHITE
KEEP, CW
TERRY, S
WELLS, M
JOURNAL OF CATALYSIS, 1980, 66 (02) : 451 - 462
[28] Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
Lv, Honggui
Kang, Huiying
Zhou, Biying
Xue, Xiaosong
Engle, Keary M.
Zhao, Dongbing
NATURE COMMUNICATIONS, 2019, 10 (1)
[29] Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
Honggui Lv
Huiying Kang
Biying Zhou
Xiaosong Xue
Keary M. Engle
Dongbing Zhao
Nature Communications, 10
[30] Nickel-catalyzed asymmetric hydrogenation of β-acylamino nitroolefins: an efficient approach to chiral amines
Gao, Wenchao
Lv, Hui
Zhang, Tonghuan
Yang, Yuhong
Chung, Lung Wa
Wu, Yun-Dong
Zhang, Xumu
CHEMICAL SCIENCE, 2017, 8 (09) : 6419 - 6422

← 1 2 3 4 5 →