Distinguishing between the Homogeneous and Heterogeneous Mechanisms of Catalysis in the Mizoroki-Heck and Suzuki-Miyaura Reactions: Problems and Prospects

被引：92
|
作者：
Schmidt, A. F. [1 ]
Kurokhtina, A. A. [1 ]
机构：
[1] Irkutsk State Univ, Fac Chem, Irkutsk 664033, Russia
来源：
KINETICS AND CATALYSIS | 2012年 / 53卷 / 06期
关键词：
SUPPORTED PALLADIUM CATALYSTS; CROSS-COUPLING REACTION; LIGAND-FREE PALLADIUM; PVP-PD NANOPARTICLES; RECYCLABLE CATALYST; ARYL IODIDES; NONCONVENTIONAL METHODOLOGIES; EFFICIENT CATALYSTS; AMBIENT CONDITIONS; ORGANIC-CHEMISTRY;
D O I：
10.1134/S0023158412060109
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review presents a critical analysis of experimental methods used in distinguishing between the homogeneous and heterogeneous catalytic mechanisms in the Mizoroki-Heck and Suzuki-Miyaura reactions. The main problems arising in the interpretation of data obtained by these methods are discussed. It is demonstrated that it is necessary to take into account the dynamics of the interconversion of molecular, nanosized, and larger palladium species that is independent of the catalyst precursor type (dissolved or solid). The role of the in situ formation of colloidal palladium particles in the case of a supported catalyst precursor is considered. DOI: 10.1134/S0023158412060109
引用
收藏
页码：714 / 730
页数：17
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