Distinguishing between the Homogeneous and Heterogeneous Mechanisms of Catalysis in the Mizoroki-Heck and Suzuki-Miyaura Reactions: Problems and Prospects

被引：92

作者：

Schmidt, A. F. ^{[1
]}

Kurokhtina, A. A. ^{[1
]}

机构：

[1] Irkutsk State Univ, Fac Chem, Irkutsk 664033, Russia

来源：

KINETICS AND CATALYSIS | 2012年 / 53卷 / 06期

关键词：

SUPPORTED PALLADIUM CATALYSTS; CROSS-COUPLING REACTION; LIGAND-FREE PALLADIUM; PVP-PD NANOPARTICLES; RECYCLABLE CATALYST; ARYL IODIDES; NONCONVENTIONAL METHODOLOGIES; EFFICIENT CATALYSTS; AMBIENT CONDITIONS; ORGANIC-CHEMISTRY;

D O I：

10.1134/S0023158412060109

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review presents a critical analysis of experimental methods used in distinguishing between the homogeneous and heterogeneous catalytic mechanisms in the Mizoroki-Heck and Suzuki-Miyaura reactions. The main problems arising in the interpretation of data obtained by these methods are discussed. It is demonstrated that it is necessary to take into account the dynamics of the interconversion of molecular, nanosized, and larger palladium species that is independent of the catalyst precursor type (dissolved or solid). The role of the in situ formation of colloidal palladium particles in the case of a supported catalyst precursor is considered. DOI: 10.1134/S0023158412060109

引用

页码：714 / 730

页数：17

共 50 条

[21] Pd- and Ni-Pyridyl Complexes Deposited as Films for Suzuki-Miyaura and Mizoroki-Heck Cross Coupling Reactions
Zhao, Xiuhua
Zhang, Jie
Zhao, Yayun
Li, Xing
CATALYSIS LETTERS, 2015, 145 (12) : 2010 - 2019
[22] Palladium nanoparticles heterogeneous nucleation within organically grafted silica foams and their use as catalyst supports toward the Suzuki-Miyaura and Mizoroki-Heck coupling reactions
Ungureanu, S.
Deleuze, H.
Babot, O.
Achard, M-F
Sanchez, C.
Popa, M. I.
Backov, R.
APPLIED CATALYSIS A-GENERAL, 2010, 390 (1-2) : 51 - 58
[23] Polyaniline-anchored palladium catalyst-mediated Mizoroki-Heck and Suzuki-Miyaura reactions and one-pot Wittig-Heck and Wittig-Suzuki reactions
Patel, Heta A.
Patel, Arun L.
Bedekar, Ashutosh V.
APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (01) : 1 - 6
[24] Synthesis, characterization, Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions of Schiff base-Pd(II) complexes
Akdeniz, Abbas
Turan, Nevin
JOURNAL OF MOLECULAR STRUCTURE, 2023, 1287
[25] Distinguishing Between Pathways for Transmetalation in Suzuki-Miyaura Reactions
Carrow, Brad P.
Hartwig, John F.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (07) : 2116 - 2119
[26] The Palladium Slow-Release Pre-Catalysts and Nanoparticles in the "Phosphine-Free" Mizoroki-Heck and Suzuki-Miyaura Reactions
Sigeev, Alexander S.
Peregudov, Alexander S.
Cheprakov, Andrei V.
Beletskaya, Irina P.
ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (2-3) : 417 - 429
[27] Magnetic dendritic polymer nanocomposites as supports for palladium: a highly efficient and reusable catalyst for Mizoroki-Heck and Suzuki-Miyaura coupling reactions
Ma, Rong
Yang, Pengbo
Bian, Fengling
NEW JOURNAL OF CHEMISTRY, 2018, 42 (06) : 4748 - 4756
[28] A highly active palladium(II)-bis(oxazoline) catalyst for Suzuki-Miyaura, Mizoroki-Heck and sonogashira coupling reactions in aqueous dimethylformamide
Ibrahim, Mansur B.
El Ali, Bassam
Fettouhi, Mohammed
Ouahab, Lahcene
APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (06) : 400 - 407
[29] Bimetallic Ni-Pd Synergism-Mixed Metal Catalysis of the Mizoroki-Heck Reaction and the Suzuki-Miyaura Coupling of Aryl Bromides
Kashid, Abhijit A.
Patil, Dharmaraj J.
Mali, Ramling D.
Patil, Vijay P.
Neethu, T. V.
Meroliya, Heena K.
Waghmode, Shobha A.
Iyer, Suresh
CATALYSIS LETTERS, 2021, 151 (02) : 353 - 358
[30] Carrier-Free and Recyclable PdCl2-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media
Tang, Boxiao
Fang, Xiaoniu
Kuang, Renyun
Cai, Jinhua
Wu, Jianhong
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (11) : 2956 - 2961

← 1 2 3 4 5 →