Distinguishing between the Homogeneous and Heterogeneous Mechanisms of Catalysis in the Mizoroki-Heck and Suzuki-Miyaura Reactions: Problems and Prospects

被引：92

作者：

Schmidt, A. F. ^{[1
]}

Kurokhtina, A. A. ^{[1
]}

机构：

[1] Irkutsk State Univ, Fac Chem, Irkutsk 664033, Russia

来源：

KINETICS AND CATALYSIS | 2012年 / 53卷 / 06期

关键词：

SUPPORTED PALLADIUM CATALYSTS; CROSS-COUPLING REACTION; LIGAND-FREE PALLADIUM; PVP-PD NANOPARTICLES; RECYCLABLE CATALYST; ARYL IODIDES; NONCONVENTIONAL METHODOLOGIES; EFFICIENT CATALYSTS; AMBIENT CONDITIONS; ORGANIC-CHEMISTRY;

D O I：

10.1134/S0023158412060109

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review presents a critical analysis of experimental methods used in distinguishing between the homogeneous and heterogeneous catalytic mechanisms in the Mizoroki-Heck and Suzuki-Miyaura reactions. The main problems arising in the interpretation of data obtained by these methods are discussed. It is demonstrated that it is necessary to take into account the dynamics of the interconversion of molecular, nanosized, and larger palladium species that is independent of the catalyst precursor type (dissolved or solid). The role of the in situ formation of colloidal palladium particles in the case of a supported catalyst precursor is considered. DOI: 10.1134/S0023158412060109

引用

页码：714 / 730

页数：17

共 50 条

[1] Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects
A. F. Schmidt
A. A. Kurokhtina
Kinetics and Catalysis, 2012, 53 : 714 - 730
[2] On the nature of the active species in palladium catalyzed Mizoroki-Heck and Suzuki-Miyaura couplings - Homogeneous or heterogeneous catalysis, a critical review
Phan, NTS
Van Der Sluys, M
Jones, CW
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (06) : 609 - 679
[3] Oxime ligands for Pd catalysis of the Mizoroki-Heck reaction, Suzuki-Miyaura coupling & annulation reactions
Bangar, Pronnoy G.
Nahide, Pradip D.
Meroliya, Heena K.
Waghmode, Shobha A.
Iyer, Suresh
SYNTHETIC COMMUNICATIONS, 2021, 51 (02) : 308 - 316
[4] Sunlight promoted palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions
Chaudhary, Anju R.
Bedekar, Ashutosh V.
TETRAHEDRON LETTERS, 2012, 53 (45) : 6100 - 6103
[5] Bio-supported palladium nanoparticles as a catalyst for Suzuki-Miyaura and Mizoroki-Heck reactions
Sobjerg, Lina Sveidal
Gauthier, Delphine
Lindhardt, Anders Thyboe
Bunge, Michael
Finster, Kai
Meyer, Rikke Louise
Skrydstrup, Troels
GREEN CHEMISTRY, 2009, 11 (12) : 2041 - 2046
[6] Palladium Nanoparticles on Graphite Oxide as Catalyst for Suzuki-Miyaura, Mizoroki-Heck, and Sonogashira Reactions
Rumi, Luigi
Scheuermann, Gil M.
Muelhaupt, Rolf
Bannwarth, Willi
HELVETICA CHIMICA ACTA, 2011, 94 (06) : 966 - 976
[7] Continuous-Flow Suzuki-Miyaura and Mizoroki-Heck Reactions under Microwave Heating Conditions
Monguchi, Yasunari
Ichikawa, Tomohiro
Yamada, Tsuyoshi
Sawama, Yoshinari
Sajiki, Hironao
CHEMICAL RECORD, 2019, 19 (01): : 3 - 14
[8] A recyclable and efficient triazole ligand for the palladium-catalyzed Suzuki-Miyaura and Mizoroki-Heck reactions
Zhu, Yi-Wei
Yi, Wen-Bin
Cai, Chun
CATALYSIS COMMUNICATIONS, 2011, 15 (01) : 118 - 122
[9] Synthesis, characterization and application of graphene palladium porphyrin as a nanocatalyst for the coupling reactions such as: Suzuki-Miyaura and Mizoroki-Heck
Bahrami, Kiumars
Kamrani, Soheila Nakhjiri
APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (02)
[10] Facile Synthesis and Characterization of Palladium@Carbon Catalyst for the Suzuki-Miyaura and Mizoroki-Heck Coupling Reactions
Alshammari, Hamed M.
Aldosari, Obaid F.
Alotaibi, Mohammad Hayal
Alotaibi, Raja L.
Alhumaimess, Mosaed S.
Morad, Moataz H.
Adil, Syed Farooq
Shaik, Mohammed Rafi
Islam, Mohammad Shahidul
Khan, Mujeeb
Alwarthan, Abdulrahman
APPLIED SCIENCES-BASEL, 2021, 11 (11):

← 1 2 3 4 5 →