The use of ultrasmall iron(0) nanoparticles as catalysts for the selective hydrogenation of unsaturated C-C bonds

被引：75

作者：

Kelsen, Vinciane ^{[1
]}

Wendt, Bianca ^{[2
]}

Werkmeister, Svenja ^{[2
]}

Junge, Kathrin ^{[2
]}

Beller, Matthias ^{[2
]}

Chaudret, Bruno ^{[1
]}

机构：

[1] Univ Toulouse, INSA, Lab Phys & Chim Nano Objets, F-31077 Toulouse, France

[2] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 33期

关键词：

HYPERTHERMIA; PARTICLES;

D O I：

10.1039/c3cc00152k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The performance of well-defined ultrasmall iron(0) nanoparticles (NPs) as catalysts for the selective hydrogenation of unsaturated C-C and C=X bonds is reported. Monodisperse iron nanoparticles of about 2 nm size are synthesized by the decomposition of {Fe(N[Si(CH3)(3)](2))(2)}(2) under dihydrogen. They are found to be active for the hydrogenation of various alkenes and alkynes under mild conditions and weakly active for C=O bond hydrogenation.

引用

页码：3416 / 3418

页数：3

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