The use of ultrasmall iron(0) nanoparticles as catalysts for the selective hydrogenation of unsaturated C-C bonds

被引：75
|
作者：
Kelsen, Vinciane [1 ]
Wendt, Bianca [2 ]
Werkmeister, Svenja [2 ]
Junge, Kathrin [2 ]
Beller, Matthias [2 ]
Chaudret, Bruno [1 ]
机构：
[1] Univ Toulouse, INSA, Lab Phys & Chim Nano Objets, F-31077 Toulouse, France
[2] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 33期
关键词：
HYPERTHERMIA; PARTICLES;
D O I：
10.1039/c3cc00152k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The performance of well-defined ultrasmall iron(0) nanoparticles (NPs) as catalysts for the selective hydrogenation of unsaturated C-C and C=X bonds is reported. Monodisperse iron nanoparticles of about 2 nm size are synthesized by the decomposition of {Fe(N[Si(CH3)(3)](2))(2)}(2) under dihydrogen. They are found to be active for the hydrogenation of various alkenes and alkynes under mild conditions and weakly active for C=O bond hydrogenation.
引用
收藏
页码：3416 / 3418
页数：3
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