A highly stereoselective synthesis of β-olivosides by glycosidations of 2-iodo-olivosyl fluoride using montmorillonite K-10 as an environmentally benign solid acid

被引：8

作者：

Toshima, K ^{[1
]}

Uehara, K ^{[1
]}

Nagai, H ^{[1
]}

Matsumura, S ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

GREEN CHEMISTRY | 2002年 / 4卷 / 01期

关键词：

D O I：

10.1039/b109172g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel and highly beta-stereoselective glycosidations of a 2-iodo-olivosyl fluoride and alcohols using a heterogeneous and environmentally benign solid acid, montmorillonite K-10, have been developed to afford the corresponding 2-iodo-beta-olivosides in high yields with high stereoselectivities.

引用

页码：27 / 29

页数：3

共 32 条

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[32] Friedel-Crafts alkylation of a cage enone:: synthesis of aralkyl substituted tetracyclo[5.3.1.0[2,6].0[4,8]]undeca-9,11-diones and the formation of fascinating novel cage compounds with pyrrole and thiophene using Montmorillonite K-10
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