A highly stereoselective synthesis of β-olivosides by glycosidations of 2-iodo-olivosyl fluoride using montmorillonite K-10 as an environmentally benign solid acid

被引:8
|
作者
Toshima, K [1 ]
Uehara, K [1 ]
Nagai, H [1 ]
Matsumura, S [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
关键词
D O I
10.1039/b109172g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The novel and highly beta-stereoselective glycosidations of a 2-iodo-olivosyl fluoride and alcohols using a heterogeneous and environmentally benign solid acid, montmorillonite K-10, have been developed to afford the corresponding 2-iodo-beta-olivosides in high yields with high stereoselectivities.
引用
收藏
页码:27 / 29
页数:3
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