Iron or nickel complexes bearing diphosphine and BIAN ligands as electrocatalysts for H2 evolution

被引：4

作者：

Budnikova, Y. H. ^{[1
]}

Khrizanforova, V. V. ^{[1
]}

Fedushkin, I. L. ^{[2
]}

Karasik, A. A. ^{[1
]}

机构：

[1] KSC RAS, AE Arbuzov Organ & Phys Chem Inst, Kazan, Russia

[2] RAS, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 11-12期

关键词：

Catalysis; iron complexes; BIAN; diazadiphosphacyclooctane; hydrogen evolution; HYDROGEN OXIDATION; CATALYSTS; WATER;

D O I：

10.1080/10426507.2016.1223664

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New effective electrocatalysts, namely iron complexes bearing diphosphine and BIAN ligands, with high catalytic hydrogen evolution rates were found. An efficient ligand substituents combination in eight-membered cyclic diphosphine containing pendant amines and innocent BIAN results in high hydrogen production rate at low catalysis potential, -0.5V ref. Fc(+)/Fc. It is possible to involve the iron complexes with diazadiphosphocyclooctane ligands in hydrogen catalysis by entering the additional redox active ligand into the coordination sphere. [GRAPHICS] .

引用

页码：1644 / 1645

页数：2

共 50 条

[31] Synthesis, characterization, and catalytic evaluation of ruthenium-diphosphine complexes bearing xanthate ligands
Aldin, Mohammed Zain
Maho, Anthony
Zaragoza, Guillermo
Demonceau, Albert
Delaude, Lionel
DALTON TRANSACTIONS, 2018, 47 (39) : 13926 - 13938
[32] Insight into the Origin of Competitive Emission of Copper(I) Complexes Bearing Diimine and Diphosphine Ligands
Yanagida, Sae
Yoshida, Masaki
Sameera, W. M. C.
Kobayashi, Atsushi
Kato, Masako
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2019, 92 (10) : 1684 - 1693
[33] Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes
Kireev, Nikolay V.
Kiryutin, Alexey S.
Pavlov, Alexander A.
Yurkovskaya, Alexandra V.
Musina, Elvira I.
Karasik, Andrey A.
Shubina, Elena S.
Ivanov, Konstantin L.
Belkova, Natalia V.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 2021 (41) : 4265 - 4272
[34] Design of molecular metal complexes with polydentate ligands for H2 production
Zhao, Xuan
Vennampalli, Mannohar
Que, Chailu
Baine, Teera
Zhang, Min
Liang, Guangchao
Xie, Chengzhi
Bollinger, John C.
Webster, Charles Edwin
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[35] Electronic and Steric Tuning of Catalytic H2 Evolution by Cobalt Complexes with Pentadentate Polypyridyl-Amine Ligands
Wang, Ping
Liang, Guangchao
Reddy, M. Ramana
Long, Melissa
Driskill, Kandria
Lyons, Christian
Donnadieu, Bruno
Bollinger, John C.
Webster, Charles Edwin
Zhao, Xuan
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (29) : 9219 - 9229
[36] Comparison of Cobalt and Nickel Complexes with Sterically Demanding Cyclic Diphosphine Ligands: Electrocatalytic H2 Production by [Co(PtBu2NPh2)(CH3CN)3](BF4)2
Wiedner, Eric S.
Yang, Jenny Y.
Dougherty, William G.
Kassel, W. Scott
Bullock, R. Morris
DuBois, M. Rakowski
DuBois, Daniel L.
ORGANOMETALLICS, 2010, 29 (21) : 5390 - 5401
[37] Cationic Platinum(II) Complexes Bearing Aryl-BIAN Ligands: Synthesis and Structural and Optoelectronic Characterization
O'Brien, Cameron
Wong, Michael Yin
Cordes, David B.
Slawin, Alexandra M. Z.
Zysman-Colman, Eli
ORGANOMETALLICS, 2015, 34 (01) : 13 - 22
[38] New aspects of H2 activation by nickel-iron hydrogenase
Pavlov, M
Blomberg, MRA
Siegbahn, PEM
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1999, 73 (02) : 197 - 207
[39] Nickel Schiff base complexes for light driven H2 production
Kiker, Meghan
Graves, Alex
Eckenhoff, William
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[40] Unraveling the catalytic mechanisms of H2 production with thiosemicarbazone nickel complexes
Barrozo, Alexandre
Orio, Maylis
RSC ADVANCES, 2021, 11 (09) : 5232 - 5238

← 1 2 3 4 5 →