Iron or nickel complexes bearing diphosphine and BIAN ligands as electrocatalysts for H2 evolution

被引：4

作者：

Budnikova, Y. H. ^{[1
]}

Khrizanforova, V. V. ^{[1
]}

Fedushkin, I. L. ^{[2
]}

Karasik, A. A. ^{[1
]}

机构：

[1] KSC RAS, AE Arbuzov Organ & Phys Chem Inst, Kazan, Russia

[2] RAS, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 11-12期

关键词：

Catalysis; iron complexes; BIAN; diazadiphosphacyclooctane; hydrogen evolution; HYDROGEN OXIDATION; CATALYSTS; WATER;

D O I：

10.1080/10426507.2016.1223664

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New effective electrocatalysts, namely iron complexes bearing diphosphine and BIAN ligands, with high catalytic hydrogen evolution rates were found. An efficient ligand substituents combination in eight-membered cyclic diphosphine containing pendant amines and innocent BIAN results in high hydrogen production rate at low catalysis potential, -0.5V ref. Fc(+)/Fc. It is possible to involve the iron complexes with diazadiphosphocyclooctane ligands in hydrogen catalysis by entering the additional redox active ligand into the coordination sphere. [GRAPHICS] .

引用

页码：1644 / 1645

页数：2

共 50 条

[11] The hydrophilic phosphatriazaadamantane ligand in the development of H2 production electrocatalysts:: Iron hydrogenase model complexes
Mejia-Rodriguez, R
Chong, DS
Reibenspies, JH
Soriaga, MP
Darensbourg, MY
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (38) : 12004 - 12014
[12] Photochemical H2 Evolution from Bis(diphosphine)nickel Hydrides Enables Low-Overpotential Electrocatalysis
Stratakes, Bethany M.
Wells, Kaylee A.
Kurtz, Daniel A.
Castellano, Felix N.
Miller, Alexander J. M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (50) : 21388 - 21401
[13] Nickel Complexes with Non-innocent Ligands as Highly Active Electrocatalysts for Hydrogen Evolution
Chen, Zhixin
Wang, Tao
Sun, Tingting
Chen, Zhiyong
Sheng, Tian
Hong, Yu-Hao
Nan, Zi-Ang
Zhu, Jun
Zhou, Zhi-You
Xia, Haiping
Sun, Shi-Gang
CHINESE JOURNAL OF CHEMISTRY, 2018, 36 (12) : 1161 - 1164
[14] Electrocatalysis of Furfural Oxidation Coupled with H2 Evolution via Nickel-Based Electrocatalysts in Water
Jiang, Nan
Liu, Xin
Dong, Jinmei
You, Bo
Liu, Xuan
Sun, Yujie
CHEMNANOMAT, 2017, 3 (07): : 491 - 495
[15] Acidities of Pt-hydroxo complexes bearing diphosphine ligands.
Upendran, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U742 - U742
[16] H2 Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation
Fourmond, Vincent
Jacques, Pierre-Andre
Fontecave, Marc
Artero, Vincent
INORGANIC CHEMISTRY, 2010, 49 (22) : 10338 - 10347
[17] Substitutional Lability of Diphosphine Ligands in Tetrahedral Iron(II) Chloro Complexes
Langer, Robert
Boenisch, Friedrich
Maser, Leon
Pietzonka, Clemens
Vondung, Lisa
Zimmermann, Thomas Philipp
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (01) : 141 - 148
[18] A Unified Theory for H2 Evolution on Mo- Based Electrocatalysts
Bau, Jeremy A.
Ahmad, Rafia
Cavallo, Luigi
Rueping, Magnus
ACS ENERGY LETTERS, 2022, 7 (10) : 3695 - 3702
[19] TRANSITION-METAL DITHIOLENE COMPLEXES .21. IRON, COBALT, AND NICKEL COMPLEXES CONTAINING CHELATING DIARSINE, DIPHOSPHINE, AND RELATED LIGANDS
MCCLEVERTY, JA
ORCHARD, DG
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (23): : 3784 - +
[20] Reducing overpotential and maintaining high rates in nickel electrocatalysts for H2 production
O'Hagan, Molly
Cardenas, Allan Jay
Appel, Aaron
Bullock, R. Morris
Wiedner, Eric
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253

← 1 2 3 4 5 →