Iron or nickel complexes bearing diphosphine and BIAN ligands as electrocatalysts for H2 evolution

被引：4

作者：

Budnikova, Y. H. ^{[1
]}

Khrizanforova, V. V. ^{[1
]}

Fedushkin, I. L. ^{[2
]}

Karasik, A. A. ^{[1
]}

机构：

[1] KSC RAS, AE Arbuzov Organ & Phys Chem Inst, Kazan, Russia

[2] RAS, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 11-12期

关键词：

Catalysis; iron complexes; BIAN; diazadiphosphacyclooctane; hydrogen evolution; HYDROGEN OXIDATION; CATALYSTS; WATER;

D O I：

10.1080/10426507.2016.1223664

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New effective electrocatalysts, namely iron complexes bearing diphosphine and BIAN ligands, with high catalytic hydrogen evolution rates were found. An efficient ligand substituents combination in eight-membered cyclic diphosphine containing pendant amines and innocent BIAN results in high hydrogen production rate at low catalysis potential, -0.5V ref. Fc(+)/Fc. It is possible to involve the iron complexes with diazadiphosphocyclooctane ligands in hydrogen catalysis by entering the additional redox active ligand into the coordination sphere. [GRAPHICS] .

引用

页码：1644 / 1645

页数：2

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