Reversible nitrogen atom transfer between nitridomanganese(V) and manganese(III) Schiff-base complexes

被引：34
|
作者：
Chang, CJ [1 ]
Low, DW [1 ]
Gray, HB [1 ]
机构：
[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125
来源：
INORGANIC CHEMISTRY | 1997年 / 36卷 / 03期
关键词：
D O I：
10.1021/ic961023a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Nitrogen atom transfer from salen-derived nitridomanganese(V) to manganese(III) Schiff-base complexes occurs under aerobic conditions in solution at room temperature. A mechanism involving chloride dissociation followed by the formation and decay of a binuclear mu-nitrido-activated complex accounts satisfactorily for the observed kinetics data.
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页码：270 / &
页数：3
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