Reversible nitrogen atom transfer between nitridomanganese(V) and manganese(III) Schiff-base complexes

被引：34

作者：

Chang, CJ ^{[1
]}

Low, DW ^{[1
]}

Gray, HB ^{[1
]}

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 03期

关键词：

D O I：

10.1021/ic961023a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nitrogen atom transfer from salen-derived nitridomanganese(V) to manganese(III) Schiff-base complexes occurs under aerobic conditions in solution at room temperature. A mechanism involving chloride dissociation followed by the formation and decay of a binuclear mu-nitrido-activated complex accounts satisfactorily for the observed kinetics data.

引用

页码：270 / &

页数：3

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