Interpenetrating frameworks in the structure of the [(SnMe3)3Re6Se8(CN)6] cluster complex

被引：3
|
作者：
Ledneva, A. Yu. [1 ]
Virovets, A. V. [1 ]
Naumov, N. G. [1 ]
机构：
[1] Russian Acad Sci, Siberian Div, AV Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 04期
关键词：
rhenium; octahedral cluster; tin; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; DATABASE; ANIONS; CHEMISTRY; COMPOUND; CATIONS; SOLIDS; IONS;
D O I：
10.1134/S0022476613040252
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single-crystal X-ray diffraction is used to determine the structure of a new compound based on an octahedral cyanide anionic cluster complex of rhenium and a trimethyltin(IV) cation: {(SnMe3)(3)[Re6Se8(CN)(6)]} (1). The crystallographic characteristics: space group C2/c, a = 13.9898(14) , b =15.334(2) , c = 20.761(2) , beta = 97.75(0)A degrees, V = 4412.91(90) (3), Z = 4, d (x) = 3.607 g/cm(3), and R = 0.0526. The compound has a framework structure; two porous frameworks with pcu topology interpenetrate each other.
引用
收藏
页码：815 / 819
页数：5
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