CRYSTAL STRUCTURE OF [Cu(NH3)2]2[{Cu(NH3)}2{Cu(NH3)(OH)}Re6Se8(CN)6]

被引：1
|
作者：
Ermolaev, A. V. [1 ]
Smolentsev, A. I. [1 ]
Mironov, Yu. V. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 62卷 / 04期
关键词：
hydrothermal synthesis; rhenium; chalcogens; octahedral cluster complex; copper; crystal structure; OCTAHEDRAL CLUSTER COMPLEXES; CHALCOCYANIDE CLUSTERS; LIGANDS SYNTHESIS; COORDINATION; POROSITY; CATIONS; ANIONS; IONS; SE;
D O I：
10.1134/S0022476621040107
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chain coordination polymer [Cu(NH3)(2)](2)[{Cu(NH3)}(2){Cu(NH3)(OH)}Re6Se8(CN)(6)] (1) is obtained by a reaction of Cs2.75K1.25[Re6Se8(CN)(4)(OH)(2)]center dot H2O with CuCN in the concentrated aqueous ammonia solution under hydrothermal conditions. The compound crystallizes in the hexagonal crystal system with the P6(3)/m space group and unit cell parameters a = 9.9902(2) angstrom, b = 9.9902(2) angstrom, c = 19.4469(7) angstrom, gamma = 120.00 degrees, V = 1680.85(8) angstrom(3), Z = 2, d(calc)= 4.661 g/cm(3). The crystal structure is composed of anionic polymer chains [{Cu(NH3)}(2){Cu(NH3)(OH)}Re6Se8(CN)(6)](2-) and complex [Cu(NH3)(2)](+) cations located in cavities. The obtained compound is characterized by single crystal X-ray diffraction, IR spectroscopy, and the elemental analysis.
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页码：585 / 589
页数：5
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