SYNTHESIS AND STUDY OF CU(NO2)2(NH3)4 AND CU(NO2)2(NH3)2

被引：0
|
作者：
CUDENNEC, Y
RIOU, A
ROCHDI, K
GERAULT, Y
LECERF, A
机构：
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1993年 / 30卷 / 1-2期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystals of Cu(NO2)2(NH3)4 and Cu(NO2)2(NH3)2 have been prepared and studied. Two allotropic species exist for each compound. alpha-Cu(NO2)2(NH3)4 is orthorhombic, space group Fmmm or Fmm2; a(angstrom) = 20.671(15), b(angstrom) = 6.796(5), c(angstrom) = 11.414(8), Z = 8. beta-Cu(NO2)2(NH3)4 is Orthorhombic, space group Cccm or Ccc2; a(angstrom) = 10.467(7), b(angstrom) = 17.766(9), c(angstrom) = 13.700(9), Z = 12. alpha-Cu(NO2)2(NH3)2 is triclinic, space group P 1BAR; a(angstrom) = 4.4165(12), b(angstrom) = 5.6104(14), c(angstrom) = 6.088(2), alpha-degrees = 78.45(3), beta-degrees = 103.95(3), gamma-degrees = 100.16(3), Z = 1. Beta-Cu(NO2)2(NH3)2 is monoclinic space group Cm or C2; a(angstrom) = 9.226(6), b(angstrom) = 7.556(3), c(angstrom) = 4.486(3), beta-degrees = 104.84(6), Z = 2.
引用
收藏
页码：77 / 85
页数：9
相关论文
共 50 条
  • [1] STRUCTURAL STUDY OF ALPHA-CU(NO2)2 (NH3)2
    ROCHDI, K
    RIOU, A
    CUDENNEC, Y
    GERAULT, Y
    LECERF, A
    [J]. EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1993, 30 (04): : 427 - 433
  • [2] Crystal structures of [Pd(NH3)3(NO2)][Rh(NH3)2(NO2)4] and [PdEn2][Rh(NH3)(NO2)5]•0.75H2O
    Khranenko, S. P.
    Kuratieva, N. V.
    Gromilov, S. A.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (03) : 498 - 502
  • [3] Crystal structures of [Pd(NH3)3(NO2)][Rh(NH3)2(NO2)4] and [PdEn2][Rh(NH3)(NO2)5]·0.75H2O
    S. P. Khranenko
    N. V. Kuratieva
    S. A. Gromilov
    [J]. Journal of Structural Chemistry, 2014, 55 : 498 - 502
  • [4] Structural study of complex [Rh(NH3)5(NO2)](NO3)2·H2O, [Rh(NH3)5(NO2)][Pd(NO2)4], and K2[Rh(NH3)(NO2)5]·H2O salts
    I. A. Baidina
    A. I. Smolentsev
    A. V. Belyaev
    [J]. Journal of Structural Chemistry, 2014, 55 : 503 - 508
  • [5] Structural study of complex [Rh(NH3)5(NO2)](NO3)2•H2O, [Rh(NH3)5(NO2)][Pd(NO2)4], and K2[Rh(NH3)(NO2)5]•H2O salts
    Baidina, I. A.
    Smolentsev, A. I.
    Belyaev, A. V.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (03) : 503 - 508
  • [6] POLARIZED CRYSTAL SPECTRA OF NI(NH3)4)NCS)2 + NI)NH3)4)NO2)2
    HARE, CR
    BALLHAUSEN, CJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (03): : 792 - &
  • [7] Thermodynamic properties and internal rotation of NH3 and NO2 groups in trans-[Pt(NH3)2(NO2)2Br2]
    Kuzina, TA
    Palkin, VA
    Golubnichaya, MA
    Kireeva, IK
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1997, 42 (11): : 1871 - 1875
  • [8] CRYSTAL STRUCTURE OF [Pd(NH3)4][Rh(NH3)(NO2)5]
    Shusharina, E. A.
    Rybinskaya, A. A.
    Plyusnin, P. E.
    Shubin, Yu V.
    Korenev, S. V.
    Gromilov, S. A.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (03) : 621 - 624
  • [9] *OPREDELENIE STRUKTURNOGO TIPA KCO(NO2)4(NH3)2
    BOKII, GB
    GILINSKAYA, EA
    [J]. DOKLADY AKADEMII NAUK SSSR, 1953, 88 (03): : 461 - 464
  • [10] CRYSTAL STRUCTURE OF [Cu(NH3)2]2[{Cu(NH3)}2{Cu(NH3)(OH)}Re6Se8(CN)6]
    Ermolaev, A. V.
    Smolentsev, A. I.
    Mironov, Yu. V.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (04) : 585 - 589
12345