Regio- and stereoselective decarbonylative carbostannylation of alkynes catalyzed by Pd/C

被引：27
|
作者：
Nakao, Y
Satoh, J
Shirakawa, E
Hiyama, T [1 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 14期
关键词：
C-C coupling; metalation; palladium; tin;
D O I：
10.1002/anie.200504283
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Out with the CO: The highly regio- and stereoselective aryl-, alkenyl-, and alkyl-stannylation of alkynes was achieved by the decarbonylative carbostannylation of propargyl 2-furoates in the presence of Pd/C. Various functionalized alkenylstannanes were obtained that contain nucleophilic alkenylstannane and electrophilic allyl furoate moieties, which can be transformed by coupling reactions. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2271 / 2274
页数：4
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