Regio- and stereoselective synthesis of (Z)-vinylgermanes by hydrogermylation of alkynes

被引：0

作者：

David-Quillot, Frank ^{[1
]}

Thiery, Valerie ^{[2
]}

Abarbri, Mohamed ^{[1
]}

Thibonnet, Jerome ^{[1
]}

Besson, Thierry ^{[2
]}

Duchene, Alain ^{[1
]}

机构：

[1] Fac Sci Tours, Lab Synth & Physicochim Organ & Therapeut, F-37200 Tours, France

[2] Univ La Rochelle, CNRS, UFR Sci Fondamentales & Sci Ingn, Lab Biotechnol & Chim Bioorgan,FRE 2766, F-17042 La Rochelle 1, France

来源：

MAIN GROUP METAL CHEMISTRY | 2007年 / 30卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have developed a new method for hydrogermylation of alkynes in alkenylgermanes. These reactions took place readily in THF under ultrasound or microwave conditions, leading to vinylgermanes with good regioselectivity and high stereoselectivity without transition metal catalysts. We demonstrated that the use of AIBN is not necessary under ultrasound or microwave conditions, and (Z)-alkenylgermane was the major product in all cases.

引用

页码：235 / 244

页数：10

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