A Novel Two-dimensional Homochiral Zinc(II) Complex Constructed Based on In Situ Ligand Formation

被引：0
|
作者：
Zhao Xiu-Qin [1 ]
Guo Chang [1 ]
Huang Rong-Yi [1 ]
Xu Heng [1 ]
Liu Guang-Xiang [1 ]
Wu Gen-Hua [1 ]
机构：
[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246003, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 10期
基金：
中国国家自然科学基金;
关键词：
zinc complex; in situ ligand synthesis; crystal structure; photoluminescence; DFT; METAL-ORGANIC FRAMEWORK; HYDROTHERMAL SYNTHESIS; LUMINESCENT PROPERTIES; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; TETRAZOLES;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel zinc(II) complex, Zn(IBT)(2) (1, HIBT = 5-(4-((1H-imidazol-1-yl)methyl)phenyl)-2H-tetrazole) has been synthesized with Zn(NO3)(2)center dot 6H(2)O, 4-(imidazol-1-ylmethyl)benzonnitrile (IBN) and NaN3 by the hydrothermal method, and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Crystallographic data for 1: C22H18N12Zn, M-r = 515.85, orthorhombic, Pbcn, a = 16.0567(15), b = 9.5316(9), c = 14.6107(14) angstrom, V = 2236.1(4) angstrom(3), Z = 4, D-c = 1.532 g/cm(3), mu = 1.138 mm(-1), F(000) = 1056, R = 0.0350 and wR = 0.0888 for 1438 observed reflections (I > 2 sigma(I)) and the goodness-of-fit S = 1.002 on F-2. The crystal structural analysis revealed that complex 1 exhibits a rare two-dimensional homochiral wave-like layer structure. In addition, the photoluminescence of complex 1 was studied in the solid state at room temperature together with its theoretical analysis.
引用
收藏
页码：1501 / 1506
页数：6
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