Structure and magnetic properties of a low-spin manganese(III) phthalocyanine dicyanide complex

被引：18
|
作者：
Matsuda, M [1 ]
Yamaura, JI
Tajima, H
Inabe, T
机构：
[1] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[2] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
来源：
CHEMISTRY LETTERS | 2005年 / 34卷 / 11期
关键词：
D O I：
10.1246/cl.2005.1524
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A manganese(III) complex salt, TPP[Mn-III(Pc)(CN)(2)](.) DCM was crystallized in dichloromethane solution (Pc = phthalocyaninato, TPP+ = tetraphenylphosphonium, and DCM = dichloromethane). In the crystal, Pc molecules form a pair of one-dimensional regular chains along the c axis. The magnetic susceptibility measurement revealed Mn ions in the low-spin state (S = 1) and a spin-orbit coupling effect due to the incomplete quenching of the angular orbital moment under the symmetrical ligand field.
引用
收藏
页码：1524 / 1525
页数：2
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