Structure and magnetic properties of a low-spin manganese(III) phthalocyanine dicyanide complex

被引：18

作者：

Matsuda, M ^{[1
]}

Yamaura, JI

Tajima, H

Inabe, T

机构：

[1] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

[2] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 11期

关键词：

D O I：

10.1246/cl.2005.1524

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A manganese(III) complex salt, TPP[Mn-III(Pc)(CN)(2)](.) DCM was crystallized in dichloromethane solution (Pc = phthalocyaninato, TPP+ = tetraphenylphosphonium, and DCM = dichloromethane). In the crystal, Pc molecules form a pair of one-dimensional regular chains along the c axis. The magnetic susceptibility measurement revealed Mn ions in the low-spin state (S = 1) and a spin-orbit coupling effect due to the incomplete quenching of the angular orbital moment under the symmetrical ligand field.

引用

页码：1524 / 1525

页数：2

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