The first evidence for activation of exogenous O2 on a vanadium(IV) center:: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate

被引：53

作者：

Kosugi, M ^{[1
]}

Hikichi, S ^{[1
]}

Akita, M ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 09期

关键词：

D O I：

10.1039/a901054h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of a vanadium(IV) hydroxo complex bearing hydrotris(3,5-diisopropylpyrazol-1-yl)borate (Tp(Pr12)) with O-2 results in reductive O-2 activation to give Tp(Pr12)V(V)(O)(eta(2)-O-2)(L); the first example of the formation of a peroxo vanadium complex from molecular oxygen.

引用

页码：1369 / 1371

页数：3

共 47 条

[41] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF HEXAVANADIUM POLYOXO ALKOXIDE ANION CLUSTERS - CRYSTAL-STRUCTURES OF THE VANADIUM(IV) SPECIES BA[V6O7(OH)3((OCH2)3CCH3)3].3H2O AND NA2[V6O7((OCH2)3CCH2CH3)4], OF THE MIXED-VALENCE COMPLEX (ME3NH)[VIV5VVO7(OH)3((OCH2)3CCH3)3], AND OF THE FLUORO DERIVATIVE NA[V6O6F(OH)3((OCH2)3CCH3)3].3H2O
KHAN, MI
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ZUBIETA, J
INORGANIC CHEMISTRY, 1993, 32 (13) : 2929 - 2937
[42] Selective synthesis, characterization, and configurational flexibility of the coordinatively unsaturated metal center of half-sandwich type complexes with the less-hindered hydrotris(3, 5-dimethyl-4-X-1-pyrazolyl)borate ligands [TpMe2,XMII(κ2-O,O′-L)] (M = Ni, Co; L = NO3, OAc; X = Me, H, Br)
Hikichi, Shiro
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Bulletin of the Chemical Society of Japan, 2002, 75 (06): : 1255 - 1262
[43] Selective synthesis, characterization, and configurational flexibility of the coordinatively unsaturated metal center of half-sandwich type complexes with the less-hindered hydrotris(3, 5-dimethyl-4-X-1-pyrazolyl)borate ligands [TpMe2,XMII(κ2-O,O′-L)] (M = Ni, Co; L = NO3, OAc; X = Me, H, Br)
Hikichi, S
Sasakura, Y
Yoshizawa, M
Ohzu, Y
Moro-oka, Y
Akita, M
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (06) : 1255 - 1262
[44] Synthesis and structural characterization of (H4APPIP)[V3(C2O4)2 (HPO4)3(PO4)(H2O)•6H2O(APPIP=1,4-bis(3-aminopropyl)piperazine), a layered vanadium oxalatophosphate containing double 6-ring units
Tang, MF
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JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (06) : 1912 - 1918
[45] Hydrothermal synthesis and structural characterization of organically-templated copper vanadium phosphates:: the two-dimensional [{Cu2(bisterpy)}V3O5(HPO4)2(PO4)] (1) and the three-dimensional [{Cu2(bisterpy)}V2O5(HPO4)2] (2) (bisterpy=2,2′:4′,4":2",2′"-quarterpyridyl,6′,6"-dipyridine)
Koo, BK
Ouellette, W
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SOLID STATE SCIENCES, 2004, 6 (05) : 461 - 468
[46] Synthesis, characterization and catalytic properties of diorganotin derivatives. Crystal and molecular structure of the first complex of 2-(2-methyl-3-nitroanilino)benzoic acid of 1,2:3,4-di-μ2-2-(2-methyl-3-nitroanilino)benzoato-O,O-1,3-bis-2-(2-methyl-3-nitroanilino)-benzoato-O-1,2,4:2,3,4-di-μ3-oxo-tetrakis[di-methyltin(IV)]
Dokorou, Vaso N.
Kovala-Demertzi, Dimitra
Louloudi, Maria
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Demertzis, Mavroudis A.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (24) : 3587 - 3592
[47] Synthesis, characterization and catalytic properties of diorganotin derivatives. Crystal and molecular structure of the first complex of 2-(2-methyl-3-nitroanilino) benzoic acid of 1,2: 3,4-di-l2-2-(2-methyl-3-nitroanilino)benzoato-O,O-1,3-bis-2-(2-methyl-3-nitroanilino)-benzoato-O-1,2,4:2,3,4-di-l3-oxo-tetrakis[di-methyltin(IV)] (vol 693, pg 3587, 2008)
Dokorou, Vaso N.
Kovala-Demertzi, Dimitra
Louloudi, Maria
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Demertzis, Mavroudis A.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (03) : 479 - 479

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