The first evidence for activation of exogenous O2 on a vanadium(IV) center:: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate

被引：53

作者：

Kosugi, M ^{[1
]}

Hikichi, S ^{[1
]}

Akita, M ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 09期

关键词：

D O I：

10.1039/a901054h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of a vanadium(IV) hydroxo complex bearing hydrotris(3,5-diisopropylpyrazol-1-yl)borate (Tp(Pr12)) with O-2 results in reductive O-2 activation to give Tp(Pr12)V(V)(O)(eta(2)-O-2)(L); the first example of the formation of a peroxo vanadium complex from molecular oxygen.

引用

页码：1369 / 1371

页数：3

共 47 条

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