The first evidence for activation of exogenous O2 on a vanadium(IV) center:: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate

被引：53
|
作者：
Kosugi, M [1 ]
Hikichi, S [1 ]
Akita, M [1 ]
Moro-oka, Y [1 ]
机构：
[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 09期
关键词：
D O I：
10.1039/a901054h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of a vanadium(IV) hydroxo complex bearing hydrotris(3,5-diisopropylpyrazol-1-yl)borate (Tp(Pr12)) with O-2 results in reductive O-2 activation to give Tp(Pr12)V(V)(O)(eta(2)-O-2)(L); the first example of the formation of a peroxo vanadium complex from molecular oxygen.
引用
收藏
页码：1369 / 1371
页数：3
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