A new designed hydrazine group-containing ruthenium complex used for catalytic hydrogenation of esters

被引：25
|
作者：
Tan, Xuefeng
Wang, Qingli
Liu, Yuanhua
Wang, Fangyuan
Lv, Hui [1 ]
Zhang, Xumu
机构：
[1] Wuhan Univ, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Hubei, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 61期
基金：
中国国家自然科学基金;
关键词：
CARBOXYLIC-ACID ESTERS; ASYMMETRIC HYDROGENATION; SELECTIVE HYDROGENATION; EFFICIENT HYDROGENATION; BIFUNCTIONAL ADDITION; CHIRAL ALCOHOLS; REDUCTION; MECHANISM; KETONES; LIGANDS;
D O I：
10.1039/c5cc04242a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydrazine group-containing nitrogen-phosphine ligand and corresponding ruthenium complexes were synthesized. When these complexes were used for hydrogenation of esters, excellent performance was observed (TON up to 17 200). A wide substrate scope was suitable for this catalytic system.
引用
收藏
页码：12193 / 12196
页数：4
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