A new designed hydrazine group-containing ruthenium complex used for catalytic hydrogenation of esters

被引：25
|
作者：
Tan, Xuefeng
Wang, Qingli
Liu, Yuanhua
Wang, Fangyuan
Lv, Hui [1 ]
Zhang, Xumu
机构：
[1] Wuhan Univ, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Hubei, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 61期
基金：
中国国家自然科学基金;
关键词：
CARBOXYLIC-ACID ESTERS; ASYMMETRIC HYDROGENATION; SELECTIVE HYDROGENATION; EFFICIENT HYDROGENATION; BIFUNCTIONAL ADDITION; CHIRAL ALCOHOLS; REDUCTION; MECHANISM; KETONES; LIGANDS;
D O I：
10.1039/c5cc04242a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydrazine group-containing nitrogen-phosphine ligand and corresponding ruthenium complexes were synthesized. When these complexes were used for hydrogenation of esters, excellent performance was observed (TON up to 17 200). A wide substrate scope was suitable for this catalytic system.
引用
收藏
页码：12193 / 12196
页数：4
相关论文
共 50 条
  • [31] New ruthenium complexes in the catalytic hydrogenation of alkynes. Study of structure and mechanism
    Shvo, Y
    Goldberg, I
    Czerkie, D
    Reshef, D
    Stein, Z
    ORGANOMETALLICS, 1997, 16 (01) : 133 - 138
  • [32] THE CHEMISTRY AND CATALYTIC PROPERTIES OF RUTHENIUM AND OSMIUM COMPLEXES .5. SYNTHESIS OF NEW COMPOUNDS CONTAINING ARSINE LIGANDS AND CATALYTIC ACTIVITY IN THE HOMOGENEOUS HYDROGENATION OF ALDEHYDES
    SANCHEZDELGADO, RA
    LEE, WY
    CHOI, SR
    CHO, YH
    JUN, MJ
    TRANSITION METAL CHEMISTRY, 1991, 16 (02) : 241 - 244
  • [33] Synthesis of Ruthenium(II) complexes containing hydroxymethylphosphines and their catalytic activities for hydrogenation of supercritical carbon dioxide
    Kayaki, Yoshihito
    Shimokawatoko, Yoshiki
    Ikariya, Takao
    INORGANIC CHEMISTRY, 2007, 46 (14) : 5791 - 5797
  • [34] Ruthenium(II) complexes containing 2-diphenylphosphinobenzaldehyde:: synthesis and catalytic activity in transfer hydrogenation
    Crochet, P
    Fernández-Zumel, MA
    Beauquis, C
    Gimeno, J
    INORGANICA CHIMICA ACTA, 2003, 356 : 114 - 120
  • [35] Novel ruthenium(II) complexes containing imino- or aminophosphine ligands for catalytic transfer hydrogenation
    Crochet, P
    Gimeno, J
    Borge, J
    García-Granda, S
    NEW JOURNAL OF CHEMISTRY, 2003, 27 (02) : 414 - 420
  • [36] Catalytic activity of a new ruthenium-(trimethylsilyl)diazomethane complex
    Lebel, H
    Paquet, V
    ORGANOMETALLICS, 2004, 23 (06) : 1187 - 1190
  • [37] Reactions of Propargyl Compounds Containing a Cyclobutyl Group Induced by a Ruthenium Complex
    Wang, Yung-Ching
    Lin, Ying-Chih
    Liu, Yi-Hung
    CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (11) : 2703 - 2710
  • [38] New catalytic oxidation of trifluoromethyl carbinols by a ruthenium(II) complex
    Kesavan, V
    Bonnet-Delpon, D
    Bégué, JP
    Srikanth, A
    Chandrasekaran, S
    TETRAHEDRON LETTERS, 2000, 41 (18) : 3327 - 3330
  • [39] Preparation carbamate of new perfluoroalkylated carbamate group-containing glycoside-based nonionic surfactants
    Trabelsi, H.
    Nasreddine, M.
    Dieng, S. Y.
    Szoenyi, S.
    TENSIDE SURFACTANTS DETERGENTS, 2007, 44 (02) : 116 - 120
  • [40] New ruthenium catalysts containing chiral Schiff bases for the asymmetric hydrogenation of acetophenone
    Karamé, I
    Jahjah, M
    Messaoudi, A
    Tommasino, ML
    Lemaire, M
    TETRAHEDRON-ASYMMETRY, 2004, 15 (10) : 1569 - 1581
12345