Preparation, chemistry, and structure of new ruthenium complexes

被引：16
|
作者：
Schneider, B [1 ]
Goldberg, I [1 ]
Reshef, D [1 ]
Stein, Z [1 ]
Shvo, Y [1 ]
机构：
[1] Tel Aviv Univ, Raymond & Beverly Sackler Sch Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 588卷 / 01期
基金：
以色列科学基金会;
关键词：
ruthenium; iodide; crystallography; synthesis; chemistry;
D O I：
10.1016/S0022-328X(99)00350-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Several new monomeric Ru iodide complexes, coordinated to the eta(5)-cylopentadienol ligand, were. prepared from the dimer complex (eta(5)-C4Ph4COHOCC4Ph4-eta(5))(mu-H)(CO)(4)Ru-2, and the monomer complex (eta(4)-C4Ph4CO)(CO)(3)Ru. Their mode of formation and chemistry were studied, and their structures were determined by X-ray diffraction analyses. In addition, two structurally interesting dimeric complexes were unexpectedly formed, and were also structurally characterized. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：92 / 98
页数：7
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