Preparation, chemistry, and structure of new ruthenium complexes

被引：16

作者：

Schneider, B ^{[1
]}

Goldberg, I ^{[1
]}

Reshef, D ^{[1
]}

Stein, Z ^{[1
]}

Shvo, Y ^{[1
]}

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Sch Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 588卷 / 01期

基金：

以色列科学基金会;

关键词：

ruthenium; iodide; crystallography; synthesis; chemistry;

D O I：

10.1016/S0022-328X(99)00350-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new monomeric Ru iodide complexes, coordinated to the eta(5)-cylopentadienol ligand, were. prepared from the dimer complex (eta(5)-C4Ph4COHOCC4Ph4-eta(5))(mu-H)(CO)(4)Ru-2, and the monomer complex (eta(4)-C4Ph4CO)(CO)(3)Ru. Their mode of formation and chemistry were studied, and their structures were determined by X-ray diffraction analyses. In addition, two structurally interesting dimeric complexes were unexpectedly formed, and were also structurally characterized. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：92 / 98

页数：7

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