Asymmetric hydrogenation of alpha, beta, and gamma-aminoketones catalyzed by cationic rhodium(I){AMPP} complexes

被引：0
|
作者：
Devocelle, M [1 ]
Agbossou, F [1 ]
Mortreux, A [1 ]
机构：
[1] UNIV SCI & TECHNOL LILLE,LAB CHIM ORGAN APPL,CTR NATL RECH SCI,URA 402,ENSCL LILLE,F-59652 VILLENEUVE DASCQ,FRANCE
来源：
SYNLETT | 1997年 / 11期
关键词：
asymmetric hydrogenation; aminophosphine-phosphinite; rhodium(I); aminoketones; aminoalcohols;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The chiral cationic rhodium aminophosphine-phosphinite complexes 4-6 were applied successfully in the asymmetric hydrogenation of alpha- (7-9), beta- (10, 11) and gamma- (12) aminoketone hydrochloride derivatives leading to the corresponding aminoalcohols in up to 97, 93, and 92 % enantiomeric excesses for the three types of substrates respectively.
引用
收藏
页码：1306 / &
页数：4
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