Asymmetric hydrogenation of alpha, beta, and gamma-aminoketones catalyzed by cationic rhodium(I){AMPP} complexes

被引：0

作者：

Devocelle, M ^{[1
]}

Agbossou, F ^{[1
]}

Mortreux, A ^{[1
]}

机构：

[1] UNIV SCI & TECHNOL LILLE,LAB CHIM ORGAN APPL,CTR NATL RECH SCI,URA 402,ENSCL LILLE,F-59652 VILLENEUVE DASCQ,FRANCE

来源：

SYNLETT | 1997年 / 11期

关键词：

asymmetric hydrogenation; aminophosphine-phosphinite; rhodium(I); aminoketones; aminoalcohols;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chiral cationic rhodium aminophosphine-phosphinite complexes 4-6 were applied successfully in the asymmetric hydrogenation of alpha- (7-9), beta- (10, 11) and gamma- (12) aminoketone hydrochloride derivatives leading to the corresponding aminoalcohols in up to 97, 93, and 92 % enantiomeric excesses for the three types of substrates respectively.

引用

页码：1306 / &

页数：4

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