Synthesis and stereochemical aspects of ethyl 1,1a,2,3,4,5,6,6a-octahydro-4-octylcyclopropa[f]indene-1-carboxylate

被引:2
|
作者
Hussain, Z
Koley, D
Hopf, H
机构
[1] Max Planck Inst Bioanorgan Chem, D-45470 Mulheim, Ruhr, Germany
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany
[3] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Ruhr, Germany
关键词
D O I
10.1002/hlca.200590262
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel approach for the synthesis of carbene adducts 9a/9b and 10/11 is reported. Identification of the geometric and positional isomers of carbene addition was carried out by reverscd-phase HPLC, and the establishment of the structure and configuration of 9a/9b was performed by means of 2D-NMR.
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页码:3263 / 3273
页数:11
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